Dr Anne Wynne-Simmons trained at the Royal Free Hospital, London, qualifying in 1971 (M.B.B.S. - Bachelor of Medicine, Bachelor of Surgery.) Always interested in children, she went on to obtain a specialist qualification in paediatrics, the Diploma in Child Health (D.C.H.), in 1973. For the next two years she worked in the highlands of Papua New Guinea treating, amongst other problems, leprosy, tuberculosis, spear and arrow wounds.

Returning to England in 1975 and aware of the effects of stress on the body, she spent two years specialising in psychiatry. She then entered General Practice, achieving Membership of the Royal College of General Practitioners (M.R.C.G.P.) in 1979. She also holds the Family Planning Certificate, and held regular clinics until 1989.

Increasingly aware of the gaps in treatment by conventional medicine, she started to explore homoeopathy. In 1983 she started working at the Royal London Homoeopathic Hospital, achieving Membership of the Faculty of Homoeopathy (M.F.Hom.) in 1985.

In 1987 she started the Homoeopathic Clinic. From 1988 she was the senior paediatrician at the Royal London Homoeopathic Hospital, resigning only for family reasons in 1994. She is a tutor in homoeopathy, training other doctors, and has appeared on behalf of homoeopathy in the national press, on radio and on television.